ChemInform Abstract: Enantioselectivity Switch in Copper‐Catalyzed Conjugate Addition Reactions under the Influence of a Chiral N‐Heterocyclic Carbene—Silver Complex. Issue 24 (27th May 2016)

• Record Type: Journal Article
• Authors: Matsumoto, Keitaro; Nakano, Yuki; Shibata, Naoatsu; Sakaguchi, Satoshi
• Is Part Of: ChemInform. Volume 47:Issue 24(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-05-27
• Subjects: diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- rings with 7 or more members -- catalysis, phase‐transfer catalysis -- reactions of organo‐metal compounds; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201624021
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The asymmetric 1, 4‐addition of diethylzinc to 2‐cycloalken‐1‐ones in presence of a copper catalyst with a chiral ligand affords 3‐ethylcycloalkanones.