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ChemInform Abstract: Synthesis of Enantiopure 1, 2‐Azido and 1, 2‐Amino Alcohols via Regio‐ and Stereoselective Ring‐Opening of Enantiopure Epoxides by Sodium Azide in Hot Water. Issue 24 (27th May 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Synthesis of Enantiopure 1, 2‐Azido and 1, 2‐Amino Alcohols via Regio‐ and Stereoselective Ring‐Opening of Enantiopure Epoxides by Sodium Azide in Hot Water. Issue 24 (27th May 2016)
Main Title:
ChemInform Abstract: Synthesis of Enantiopure 1, 2‐Azido and 1, 2‐Amino Alcohols via Regio‐ and Stereoselective Ring‐Opening of Enantiopure Epoxides by Sodium Azide in Hot Water.
Abstract: The ring‐opening of enantiopure aryl epoxides by azide anion takes place preferentially at the internal position to produce 2‐azido ethanols with high regio‐ and enantioselectivity.