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ChemInform Abstract: Efficient Synthesis of Chiral Trisubstituted 1, 2‐Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes. Issue 22 (12th May 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Efficient Synthesis of Chiral Trisubstituted 1, 2‐Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes. Issue 22 (12th May 2016)
Main Title:
ChemInform Abstract: Efficient Synthesis of Chiral Trisubstituted 1, 2‐Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes.
Abstract: The conjugate addition of malonic esters to enynes in the presence of a scandium(III)/N, N‐dioxide complex yields a range of trisubstituted allenyl ketones with good diastereomeric ratios and excellent e.e.‐values.