Compression of Fe–Si–H alloys to core pressures. Issue 8 (22nd April 2016)

• Record Type: Journal Article
• Authors: Tagawa, Shoh; Ohta, Kenji; Hirose, Kei; Kato, Chie; Ohishi, Yasuo
• Is Part Of: Geophysical research letters. Volume 43:Issue 8(2016)
• Page Start: 3686
• Page End: 3692
• Publication Date: 2016-04-22
• Subjects: hydrogen -- iron alloy -- equation of state -- compressibility -- core -- high pressure; Geophysics -- Periodicals; Planets -- Periodicals; Lunar geology -- Periodicals; 550
• DOI: 10.1002/2016GL068848
• Languages: English
• ISSNs: 0094-8276

Abstract

Abstract: We examined the compression behavior of hexagonal‐close‐packed (hcp) (Fe0.88 Si0.12 )1 H0.61 and (Fe0.88 Si0.12 )1 H0.79 (in atomic ratio) alloys up to 138 GPa in a diamond anvil cell (DAC). While contradicting experimental results were previously reported on the compression curve of double‐hcp (dhcp) FeH x ( x ≈ 1), our data show that the compressibility of hcp Fe0.88 Si0.12 H x alloys is very similar to those of hcp Fe and Fe0.88 Si0.12, indicating that the incorporation of hydrogen into iron does not change its compression behavior remarkably. The present experiments suggest that the inner core may contain up to 0.47 wt % hydrogen (FeH0.26 ) if temperature is 5000 K. The calculated density profile of Fe0.88 Si0.12 H0.17 alloy containing 0.32 wt % hydrogen in addition to geochemically required 6.5 wt % silicon matches the seismological observations of the outer core, supporting that hydrogen is an important core light element. Key Points: Compressibility of hcp Fe0.88 Si0.12 H x ( x = 0.61 and 0.79) was examined up to 138 GPa Compression behavior of Fe0.88 Si0.12 H x is similar to that of hcp pure Fe and Fe0.88 Si0.12 Density profile of Fe0.88 Si0.12 H0.17 matches the PREM for the outer core