Direct Perfluoroalkylthiolation of Few Chalcogenols. Issue 5 (8th March 2016)

• Record Type: Journal Article
• Authors: Glenadel, Quentin; Billard, Thierry
• Is Part Of: Chinese journal of chemistry. Volume 34:Issue 5(2016:May)
• Page Start: 455
• Page End: 458
• Publication Date: 2016-03-08
• Subjects: perfluoroalkylthiolation -- perfluoroalkyldisulfide -- perfluoroalkanesulfenate -- trifluoromethylthiolation -- trifluoromethanesulfenamide; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cjoc.201500913
• Languages: English
• ISSNs: 1001-604X

Abstract

Abstract: Trifluoromethanesulfenamide reagent can react with alcohols, in basic conditions, or with thiols, in catalytic acid conditions, to afford the corresponding trifluoromethanesulfenates or trifluoromethyldisulfides. The use of higher homologs of this reagent leads to synthesis of the nearly unknown perfluoroalkanesulfenates and perfluoroalkyldisulfides. Abstract : 2nd generation of perfluoroalkanesulfenamides reagents can react with chalcogenols in basic or catalytic acid conditions to give the corresponding perfluoroalkylthiochalcogenides still little described this day.