ChemInform Abstract: Enantioselective Catalysts for the Synthesis of α‐Substituted Allylboronates — An Accelerated Approach Towards Isomerically Pure Homoallylic Alcohols. Issue 22 (12th May 2016)

• Record Type: Journal Article
• Authors: Brauns, Marcus; Muller, Frederic; Guelden, Daniel; Boese, Dietrich; Frey, Wolfgang; Breugst, Martin; Pietruszka, Joerg
• Is Part Of: ChemInform. Volume 47:Issue 22(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-05-12
• Subjects: diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- organo‐boron compounds -- e/z‐selectivity (incl. e/z‐isomerism) -- alcohols (acyclic compounds) -- C‐C bond formation; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201622027
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Enantiopure bis(allylboronates) (V) and (VIII) are synthesized using a Cu‐catalyzed SN 2′ reaction of tartrate based bisboronate (III) with Grignard reagents in the presence of the chiral phosphoramidite ligand.