Amide exchange reaction: a simple and efficient CuO catalyst for diacetamide synthesis. Issue 47 (25th April 2016)
- Record Type:
- Journal Article
- Title:
- Amide exchange reaction: a simple and efficient CuO catalyst for diacetamide synthesis. Issue 47 (25th April 2016)
- Main Title:
- Amide exchange reaction: a simple and efficient CuO catalyst for diacetamide synthesis
- Authors:
- Li, Qinghe
Wang, Peixue
Deng, Youquan - Abstract:
- Abstract : Synthesis of hexamethylenebisacetamide (HMBA) from hexamethylenediamine (HDA), CH3 CN and H2 O catalyzed by CuO without an organic solvent and gas protection. Abstract : A highly copper-catalysed amide exchange reaction of hexamethylenediamine (HDA) with CH3 CN and H2 O for the synthesis of hexamethylenebisacetamide (HMBA) without an organic solvent or gas protection was developed. 100% HDA conversion and >99% HMBA selectivity was obtained. X-ray diffraction, scanning emission microscopy, and temperature-programmed reduction of hydrogen were used to characterize the structural properties of the catalyst. The reaction mechanism was also investigated.
- Is Part Of:
- RSC advances. Volume 6:Issue 47(2016)
- Journal:
- RSC advances
- Issue:
- Volume 6:Issue 47(2016)
- Issue Display:
- Volume 6, Issue 47 (2016)
- Year:
- 2016
- Volume:
- 6
- Issue:
- 47
- Issue Sort Value:
- 2016-0006-0047-0000
- Page Start:
- 40890
- Page End:
- 40894
- Publication Date:
- 2016-04-25
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/RA ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6ra05563j ↗
- Languages:
- English
- ISSNs:
- 2046-2069
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8036.750300
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2760.xml