Safe P4 reagent in a reusable porous coordination network. Issue 15 (23rd March 2016)

• Record Type: Journal Article
• Authors: Choi, Wanuk; Ohtsu, Hiroyoshi; Matsushita, Yoshitaka; Kawano, Masaki
• Is Part Of: Dalton transactions. Volume 45:Issue 15(2016)
• Page Start: 6357
• Page End: 6360
• Publication Date: 2016-03-23
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt00860g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : P4 generated from red phosphorus via the gas phase was trapped into an interactive pore of a porous coordination network, showing weak interactions which stabilize the reactive P4 in a pore. Abstract : P4 generated from red phosphorus via the gas phase was trapped into an interactive pore of a porous coordination network, showing weak interactions which stabilize the reactive P4 in a pore. The network is reusable as a safe container of P4 . Furthermore, we found a size dependence of the P4 trapping amount: for 100–50 μm crystal, 27% occupancy of P4 ; and for <20 μm crystal, ca . 93% occupancy of P4 .