Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis. Issue 38 (21st March 2016)
- Record Type:
- Journal Article
- Title:
- Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis. Issue 38 (21st March 2016)
- Main Title:
- Operationally simple hydrotrifluoromethylation of alkenes with sodium triflinate enabled by Ir photoredox catalysis
- Authors:
- Zhu, Lei
Wang, Lian-Sheng
Li, Bojie
Fu, Boqiao
Zhang, Cheng-Pan
Li, Wei - Abstract:
- Abstract : A single component Ir photoredox catalyst was developed in order to catalyze the hydrotrifluoromethylation of terminal alkenes and Michael acceptors with sodium triflinate. Abstract : We report herein a single component Ir photoredox catalyst which is capable of catalyzing the hydrotrifluoromethylation of terminal alkenes and Michael acceptors with sodium triflinate (Langlois reagent) in methanol under irradiation at room temperature. Various synthetically useful functional groups, including ester, amide, ether, aldehyde, sulfone, ketone and aryl boronate, are well tolerated in this reaction.
- Is Part Of:
- Chemical communications. Volume 52:Issue 38(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 38(2016)
- Issue Display:
- Volume 52, Issue 38 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 38
- Issue Sort Value:
- 2016-0052-0038-0000
- Page Start:
- 6371
- Page End:
- 6374
- Publication Date:
- 2016-03-21
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc01944g ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2722.xml