Methyl NFSI: atom-economical alternative to NFSI shows higher fluorination reactivity under Lewis acid-catalysis and non-catalysis. Issue 7 (1st December 2015)

• Record Type: Journal Article
• Authors: Fukushi, Kazunobu; Suzuki, Satoru; Kamo, Tomohiro; Tokunaga, Etsuko; Sumii, Yuji; Kagawa, Takumi; Kawada, Kosuke; Shibata, Norio
• Is Part Of: Green chemistry. Volume 18:Issue 7(2016)
• Page Start: 1864
• Page End: 1868
• Publication Date: 2015-12-01
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/c5gc02612a
• Languages: English
• ISSNs: 1463-9262

Abstract

Abstract : Me-NFSI is more effective for the fluorination of active methines under Lewis acid-catalysis and non-catalysis than NFSI. Abstract : Me-NFSI was first reported in 1994. Despite its atom-economical structure and similarity to a well-explored fluorinating reagent, NFSI, Me-NFSI has not appeared in the literature in over 20 years. We disclose that Me-NFSI is more effective for the fluorination of active methines under Lewis acid-catalysis and non-catalysis than NFSI.