Epoxy resin reinforced with nanothin polydopamine-coated carbon nanotubes: a study of the interfacial polymer layer thickness. Issue 37 (29th March 2016)

• Record Type: Journal Article
• Authors: Ling, Yang; Li, Weizhen; Wang, Baoyu; Gan, Wenjun; Zhu, Chenhui; Brady, Michael A.; Wang, Cheng
• Is Part Of: RSC advances. Volume 6:Issue 37(2016)
• Page Start: 31037
• Page End: 31045
• Publication Date: 2016-03-29
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra26539h
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Carbon nanotubes (CNTs) functionalized by a nanothin poly(dopamine) (PDA) layer were produced by a one-pot, nondestructive approach, with direct polymerization of dopamine on the CNT surface. Abstract : Carbon nanotubes (CNTs) functionalized by a nanothin poly(dopamine) (PDA) layer were produced by a one-pot, nondestructive approach, with direct polymerization of dopamine on the CNT surface. The thickness of the PDA layer can be well-controlled by the reaction time and the proportion of dopamine, and this thickness is found to be the key factor in controlling the dispersion of CNTs and the extent of the interfacial interactions between the CNT@PDA and epoxy resin. SEM results indicated that the dispersion of CNTs in epoxy was improved significantly by coating a nanothin PDA layer onto the CNT surface. In agreement with this finding, the CNTs functionalized with the thinnest PDA layer provided the best mechanical and thermal properties. This result confirmed that a thinner PDA layer could provide optimized interfacial interactions between the CNT@PDA and epoxy matrix and weaken the self-agglomeration of CNTs, which led to an improved effective stress and heat transfer between the CNTs and the polymer matrix.