Fluorescence behavior of 5, 10-disubstituted [5]helicene derivatives in solution and the effect of self-assembly on their radiative and non-radiative rate constants. Issue 14 (10th February 2016)

• Record Type: Journal Article
• Authors: Hirose, Takashi; Ito, Natsuki; Kubo, Hiromu; Sato, Tohru; Matsuda, Kenji
• Is Part Of: Journal of materials chemistry. Volume 4:Issue 14(2016)
• Page Start: 2811
• Page End: 2819
• Publication Date: 2016-02-10
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5tc03675e
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Fluorescence behavior of 5, 10-disubstituted [5]helicene derivatives is sensitive to the type of substituent and the motif of self-assembly in the solution phase. Abstract : The surrounding environment of a molecular fluorophore is one of the most important determining factors in luminescence properties, such as the emission quantum yield, the lifetime of the excited state, and the color of luminescence. In this work, we investigate the relationship between the self-assembled structure and the fluorescence properties of [5]helicene derivatives in the solution phase. A [5]Helicene derivative bearing the tri(ethylene glycol) group formed spherical aggregates in aqueous media and that bearing the (3, 4, 5-trioctyloxyphenyl)carbamoyl group formed fibrous aggregates in apolar solvent. Analysis based on the radiative ( k f ) and non-radiative ( k nr ) rate constants suggests that (1) an aggregation-induced suppression of fluorescence observed in aqueous media is attributed to the decrease of k f, (2) an aggregation-induced enhancement of fluorescence observed for fibrous aggregates formed in an apolar solvent is associated with the suppression of k nr, (3) [5]helicenes become almost non-fluorescent especially in a polar solvent by introducing an appropriate donor substituent due to a charge-transfer (CT) type property in the lowest energy excited state, and (4) the strong quenching effect due to the CT-type excitation can be efficiently alleviated by several approaches, such as by forming aggregates with an appropriate self-assembly motif or by controlling the energy level of molecular orbitals.