Palladium‐Catalyzed Oxidative Synthesis of α‐Acetoxylated Enones from Alkynes. (6th April 2016)
- Record Type:
- Journal Article
- Title:
- Palladium‐Catalyzed Oxidative Synthesis of α‐Acetoxylated Enones from Alkynes. (6th April 2016)
- Main Title:
- Palladium‐Catalyzed Oxidative Synthesis of α‐Acetoxylated Enones from Alkynes
- Authors:
- Jiang, Tuo
Quan, Xu
Zhu, Can
Andersson, Pher G.
Bäckvall, Jan‐E. - Abstract:
- Abstract: We report a palladium‐catalyzed oxidative functionalization of alkynes to generate α‐acetoxylated enones in one step. A range of functional groups are well‐tolerated in this reaction. Mechanistic studies, including the use of 18 O‐labeled DMSO, revealed that the ketone oxygen atom in the product originates from DMSO.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 19(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 19(2016)
- Issue Display:
- Volume 128, Issue 19 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 19
- Issue Sort Value:
- 2016-0128-0019-0000
- Page Start:
- 5918
- Page End:
- 5922
- Publication Date:
- 2016-04-06
- Subjects:
- Alkine -- Enone -- Oxidationen -- Palladium -- Sulfoxide
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201600696 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 501.xml