SnO2Gold Nanoparticle@Polyhedral Oligomeric Silsesquioxane Hybrid Scaffolds in Microfluidic Format – Highly Efficient and Green Catalytic Platforms (Eur. J. Inorg. Chem. 7/2016). Issue 7 (March 2016)

• Record Type: Journal Article
• Authors: Scholder, Pascal; Hafner, Martina; Hassel, Achim W.; Nischang, Ivo
• Is Part Of: European journal of inorganic chemistry. Issue 7(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-03
• Subjects: Continuous flow reactors -- Supported catalysts -- Nanoparticles -- Gold -- Organic–inorganic hybrid composites -- Miniaturization; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201690014
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract : The cover picture shows the conceptual approach to miniaturized flow chemistry enabled by highly porous hybrid materials created in situ from polyhedral oligomeric silsesquioxanes (POSS). The materials contain gold nanoparticles that are strongly held within their porous structure by thiol–gold interactions. The tubular reactors are operated with an aqueous liquid phase at room temperature. The size of the gold nanoparticles and the pore size of the scaffolds themselves can be tailored to create highly efficient platforms for small‐scale chemical processes using the "green" solvent water. Details are discussed in the Communication by I. Nischang et al. onp. 951 ff . For more on the story behind the cover research, see theCover Profile .