Assorted Phenoxyl‐Radical Polymers and Their Application in Lithium‐Organic Batteries. Issue 8 (3rd March 2016)

• Record Type: Journal Article
• Authors: Jähnert, Thomas; Hager, Martin D.; Schubert, Ulrich S.
• Is Part Of: Macromolecular rapid communications. Volume 37:Issue 8(2016)
• Page Start: 725
• Page End: 730
• Publication Date: 2016-03-03
• Subjects: antioxidants -- phenoxyl electrochemistry -- redox polymers; Macromolecules -- Periodicals; Polymers -- Periodicals; Chemistry -- Periodicals; 547.705
• DOI: 10.1002/marc.201500702
• Languages: English
• ISSNs: 1022-1336

Abstract

Abstract : The synthesis and electrochemical characterization of novel polymers bearing phenoxyl‐radicals as redox‐active side chains is described. The monomers are synthesized from the corresponding phenols and quinones, respectively. These compounds are subsequently poly­merized via ring‐opening metathesis polymerization. The electrochemical properties of the phenoxyl‐radical polymers are characterized using cyclic voltammetry and the most promising polymer is investigated as active material in a lithium coin‐cell, creating the first phenoxyl‐lithium battery. These phenoxyl‐containing polymers represent interesting anode materials for organic radical and lithium batteries due to their suitable redox‐potentials and possibility to create batteries with higher potentials as well as straightforward synthesis procedures. Abstract : The synthesis and electrochemical characterization of polymers, which bear phenoxyl‐radicals, is described. The monomers, synthesized from the corresponding phenols or quinones, are poly­merized using ring‐opening metathesis polymerization procedures. The phenoxyl‐radical polymers are characterized electrochemically via cyclic voltammetry. The most promising polymer is tested in a lithium‐organic battery. These batteries are tested for their charge‐ and discharge‐behavior and showed promising results.