Graphene Oxide Liquid Crystals: Discovery, Evolution and Applications. Issue 16 (1st March 2016)

• Record Type: Journal Article
• Authors: Narayan, Rekha; Kim, Ji Eun; Kim, Ju Young; Lee, Kyung Eun; Kim, Sang Ouk
• Is Part Of: Advanced materials. Volume 28:Issue 16(2016)
• Page Start: 3045
• Page End: 3068
• Publication Date: 2016-03-01
• Subjects: graphene -- liquid crystals -- graphene oxide -- nematic -- colloids; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201505122
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract : The discovery and relevant research progress in graphene oxide liquid crystals (GOLCs), the latest class of 2D nanomaterials exhibiting colloidal liquid crystallinity arising from the intrinsic disc‐like shape anisotropy, is highlighted. GOLC has conferred a versatile platform for the development of novel properties and applications based on the facile controllability of molecular scale alignment. The first part of this review offers a brief introduction to LCs, including the theoretical background. Particular attention has been paid to the different types of LC phases that have been reported thus far, such as nematic, lamellar and chiral phases. Several key parameters governing the ultimate stability of GOLC behavior, including pH and ionic strength of aqueous dispersions are highlighted. In a relatively short span of time since its discovery, GOLCs have proved their remarkable potential in a broad spectrum of applications, including highly oriented wet‐spun fibers, self‐assembled nanocomposites, and architectures for energy storage devices. The second part of this review is devoted to an exclusive overview of the relevant applications. Finally, an outlook is provided into this newly emerging research field, where two well established scientific communities for carbon nanomaterials and liquid crystals are ideally merged. Abstract : Graphene oxide liquid crystals (GOLCs) attract widespread research attention simultaneously from graphene research communities and liquid crystal scientists. Discovery of GOLC mesophases, recent progress and latest exploration in different application fields are highlighted.