ChemInform Abstract: Microwave‐Assisted Organocatalyzed Rearrangement of Propargyl Vinyl Ethers to Salicylaldehyde Derivatives: An Experimental and Theoretical Study. Issue 17 (April 2016) - Tejedor, David
Abstract: According to a DFT study on a simplified model, the reaction proceeds via a domino process comprising a [3, 3]‐propargyl Claisen rearrangement, a [1, 3]—H shift, a [1, 7]—H shift (enolization), a 6π electrocyclization, and an aromatization step.