ChemInform Abstract: Iodine‐Mediated Copper‐Catalyzed Efficient α‐C(sp2)‐Thiomethylation of α‐Oxoketene Dithioacetals with Dimethyl Sulfoxide in One Pot. Issue 17 (April 2016)

• Record Type: Journal Article
• Authors: Shukla, Gaurav; Srivastava, Abhijeet; Nagaraju, Anugula; Raghuvanshi, Keshav; Singh, Maya Shankar
• Is Part Of: ChemInform. Volume 47:Issue 17(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-04
• Subjects: mercaptans, thioethers (acyclic compounds) -- sulfuration, sulfonation, S‐alkylation -- catalysis, phase‐transfer catalysis -- ketones (acyclic compounds) -- ketones (benzene compounds); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201617078
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: This operationally simple one‐pot protocol includes region‐defined consecutive iodination and sulfenylation of the challenging α‐C(sp 2 )—H bond of dithioacetals employing cheap and readily available reagents.