ChemInform Abstract: Highly Diastereoselective Synthesis of Methylenecyclobutanes by Merging Boron‐Homologation and Boron‐Allylation Strategies. Issue 17 (April 2016)

• Record Type: Journal Article
• Authors: Eisold, Michael; Didier, Dorian
• Is Part Of: ChemInform. Volume 47:Issue 17(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-04
• Subjects: cyclobutane derivatives -- diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- C‐C bond formation; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201617079
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The uncatalyzed reaction of cyclobutenylmethyl boron compounds (I) and (IV) with aldehydes results in the efficient formation of methylene cyclobutanes (III) and (V).