ChemInform Abstract: Highly Enantioselective Aza‐Michael Reaction Between Alkyl Amines and β‐Trifluoromethyl β‐Aryl Nitroolefins. Issue 17 (April 2016)

• Record Type: Journal Article
• Authors: Wang, Leming; Chen, Jiean; Huang, Yong
• Is Part Of: ChemInform. Volume 47:Issue 17(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-04
• Subjects: amines (benzene compounds) -- addition reactions -- diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- organocatalysis; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201617083
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Chiral N‐heterocyclic carbenes are used as noncovalent organocatalysts for the highly selective aza‐Michael addition between primary alkyl amines and various nitroolefins affording chiral trifluoromethylated amines.