ChemInform Abstract: New Lanthanide Mixed‐Valent Vanadium(III/IV) Oxosilicates, Ln4V5‐xZnxSi4O22 (Ln: La, Ce, Pr, and Nd), Crystallizing in a Quasi Two‐Dimensional Rutile‐Based Structure. Issue 18 (April 2016)

• Record Type: Journal Article
• Authors: Abeysinghe, Dileka; Smith, Mark D.; Yeon, Jeongho; Morrison, Gregory; zur Loye, Hans‐Conrad
• Is Part Of: ChemInform. Volume 47:Issue 18(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-04
• Subjects: vanadium, V -- lanthanoids -- structure (solids and liquids) -- zinc, Zn -- silicon, Si -- dielectric properties, magnetic properties; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201618019
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Single crystals of the title compounds are grown via a molten flux method employing a 1:2:2 molar mixture of Ln2 O3, V2 O5, and Zn in a eutectic CsCl/NaCl mixture (evacuated silica tubes acting as Si source, 1000 °C, 24 h).