Synthesis, Crystal Structure, and Catalytic Property of a Copper(II) Complex Derived From 2-Hydroxy-5-Methoxybenzaldehyde Oxime. Issue 3 (3rd March 2016)

• Record Type: Journal Article
• Authors: Shen, Xi-Hai; Zhang, Zhi-Wei; Shao, Li-Jun; Lian, Qi; Liu, Chun
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 3(2016)
• Page Start: 343
• Page End: 346
• Publication Date: 2016-03-03
• Subjects: Schiff base -- copper complex -- crystal structure -- catalytic property; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2014.988246
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : With a bidentate Schiff base ligand 2-hydroxy-5-methoxybenzaldehyde oxime (HL) and copper acetate, a polynuclear copper(II) complex was prepared and characterized by elemental analysis, IR spectroscopy, and X-ray structure determination. The complex crystallizes in the orthorhombic space group Pbca with unit cell dimensions a = 7.5094(7) Å, b = 6.5131(7) Å, c = 33.081(3) Å, V = 1618.0(3) Å 3, Z = 4, R 1 = 0.0628, and wR 2 = 0.1194. Single-crystal X-ray diffraction analysis reveals that the Cu atom is coordinated by two imino N, two phenolate O, and two oxime O atoms from two Schiff base ligands, in an octahedral coordination. Catalytic oxidation of the complex on some olefins was performed.