Hydrothermal Synthesis and Structural Characterization of a Three-Dimensional Coordination Polymer on Ag(I). Issue 5 (3rd May 2016)

• Record Type: Journal Article
• Authors: Chen, Qi; Lun, Hui-Jie; Li, Yong-Hong; Li, Shu; Li, Bei-Bei; Zhang, Xu-Dong; Li, Ya-Min
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 5(2016)
• Page Start: 730
• Page End: 734
• Publication Date: 2016-05-03
• Subjects: 1, 2, 4-benzenetricarboxylate -- coordination polymer -- luminescent property; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2014.989582
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : A new coordination polymer [Ag3 (1, 2, 4-btc)]n (1 ) (1, 2, 4-H3 btc = 1, 2, 4-benzenetricarboxylate) has been synthesized by hydrothermal method and characterized by X-ray single crystal diffraction, elemental analysis, IR spectrum, and TGA. Compound1 exhibits a 3D network consisting of the 2D layer connected by the ligand 1, 2, 4-btc 3−, which adopts a new coordination mode. Moreover, blue fluorescence at 480 nm emission was observed under 320 nm excitation.