Cycloaddition reaction of spiro[2.4]hepta-4, 6-dien-1-ylmethanol and PTAD: a new rearrangement. Issue 20 (19th May 2016)
- Record Type:
- Journal Article
- Title:
- Cycloaddition reaction of spiro[2.4]hepta-4, 6-dien-1-ylmethanol and PTAD: a new rearrangement. Issue 20 (19th May 2016)
- Main Title:
- Cycloaddition reaction of spiro[2.4]hepta-4, 6-dien-1-ylmethanol and PTAD: a new rearrangement
- Authors:
- Şenol, Halil
Bayrak, Çetin
Menzek, Abdullah
Şahin, Ertan
Karakuş, Murat - Abstract:
- Abstract: Reaction of spiro[2.4]hepta-4, 6-dien-1-ylmethanol (3) with phenyltriazolinedione (PTAD) gave 4-phenyl-1-[(3a R ( S ), 6 S ( R ))-1a, 2, 3a, 6-tetrahydro-1 H -cyclopenta[ b ]cyclopropa[ c ]furan-6-yl]-1, 2, 4-triazolidine-3, 5-dione (7 ) via a novel rearrangement. The structure of this rearranged product was determined by spectroscopic methods and by experimentation. Influences of functional groups on the rearrangement and formation of7 were discussed. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 72:Issue 20(2016)
- Journal:
- Tetrahedron
- Issue:
- Volume 72:Issue 20(2016)
- Issue Display:
- Volume 72, Issue 20 (2016)
- Year:
- 2016
- Volume:
- 72
- Issue:
- 20
- Issue Sort Value:
- 2016-0072-0020-0000
- Page Start:
- 2587
- Page End:
- 2592
- Publication Date:
- 2016-05-19
- Subjects:
- Cyclopropylmethanol -- Cycloaddition -- Phenyltriazolinedione -- Rearrangement -- Spirocyclopentadiene
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2016.03.094 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2190.xml