Effect of Glucose on the Synthesis of Iron Carbide Nanoparticles from Combustion Synthesis Precursors. Issue 4 (1st February 2016)

• Record Type: Journal Article
• Authors: Gu, Yueru; Qin, Mingli; Cao, Zhiqin; Jia, Baorui; Wang, Xuanli; Qu, Xuanhui
• Editors: Joy, Pattayil A
• Is Part Of: Journal of the American Ceramic Society. Volume 99:Issue 4(2016)
• Page Start: 1443
• Page End: 1448
• Publication Date: 2016-02-01
• Subjects: Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.14117
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract : Iron carbide (Fe3 C) nanoparticles have been successfully synthesized by combining low‐temperature combustion synthesis method with carbothermal reduction. A homogeneous precursor powder (Fe2 O3 + C) derived from iron nitrate, glycine, and glucose mixed solution was subsequently calcined under nitrogen at 450°C–700°C for 2 h. Effects of glucose on the size and morphology of the precursors as well as the synthesized Fe3 C powders were studied in details. The results showed a regular variation in the particle size and morphology of the precursors and Fe3 C powders with the increasing molar ratio of glucose to iron nitrate (G/Fe). XRD analysis indicated that the initial transformation of the precursor for (G/Fe = 1) to Fe3 C occurred at 500°C. Meanwhile, magnetic properties of the Fe3 C have been tested by vibrating sample magnetometer (VSM). The saturation magnetization (Ms) of Fe3 C powders synthesized using different G/Fe ratios (G/Fe = 1, 2, 3) was 51.2, 37.0, and 27.1 emu/g, respectively. This made the Fe3 C a promising candidate for magnetic materials.