ChemInform Abstract: Enantioselective Direct Aldol Reactions Promoted by Phosphine Oxide Aziridinyl Phosphonate Organocatalysts. Issue 16 (March 2016)

• Record Type: Journal Article
• Authors: Dogan, Oezdemir; Tan, Duygu
• Is Part Of: ChemInform. Volume 47:Issue 16(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-03
• Subjects: diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- organocatalysis; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201616025
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The phosphonate POAP is tested as a chiral catalyst in the aldol reaction of cyclohexanone with aldehydes (II), however, the yield, diastereoselectivity, and enantioselectivity are only low to moderate.