Zn(ii) porphyrin based nano-/microscale metal–organic frameworks: morphology dependent sensitization and photocatalytic oxathiolane deprotection. Issue 31 (10th March 2016)

• Record Type: Journal Article
• Authors: Zhao, Fang-Yao; Li, Wen-Juan; Guo, An; Chang, Lan; Li, Yue; Ruan, Wen-Juan
• Is Part Of: RSC advances. Volume 6:Issue 31(2016)
• Page Start: 26199
• Page End: 26202
• Publication Date: 2016-03-10
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra01599a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Zn(ii ) porphyrin based nano-/microscale MOFs showed morphology dependent 1 O2 sensitization efficiency and were used as selective photocatalysts for oxathiolane deprotection. Abstract : With Zn(ii ) porphyrin as a building block, nano-/microscale MOFs with different morphologies were synthesized as sensitizers for O2 (forming 1 O2 ). The sensitization efficiency was observed to enhance remarkably with the decrease of morphological dimension of the sample. With high sensitization ability, the one-dimensional MOF could selectively photocatalyze the deprotection of oxathiolanes to ketones.