ChemInform Abstract: Photoinduced Decarbonylative Rearrangement of Bicyclo[2.2.2]octenones: Synthesis of the Marasmane Skeleton. Issue 11 (February 2016)

• Record Type: Journal Article
• Authors: Wang, Chun‐Chieh; Ku, Yi‐Chen; Chuang, Gary Jing
• Is Part Of: ChemInform. Volume 47:Issue 11(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-02
• Subjects: photochemistry, radiation chemistry, chemoluminescence -- rearrangements -- terpenes; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201611035
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The fused‐5, 6, 3‐tricyclic ring structure of the marasmane sesquiterpenoid skeleton is formed via a photo‐induced decarbonylative 1, 3‐migration reaction of bicyclo[2.2.2]octenone derivatives such as (I), (III), and (V).