Copper(II) Triflate‐Catalyzed Aerobic Oxidative CH Functionalization of Glycine Derivatives with Olefins and Organoboranes. Issue 6 (15th February 2016)

• Record Type: Journal Article
• Authors: Xie, Zhiyu; Jia, Jiong; Liu, Xigong; Liu, Lei
• Is Part Of: Advanced synthesis & catalysis. Volume 358:Issue 6(2016)
• Page Start: 919
• Page End: 925
• Publication Date: 2016-02-15
• Subjects: aerobic oxidation -- CH functionalization -- copper -- olefins -- organoborane.; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201501015
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: An economical, and practical copper(II) triflate‐catalyzed aerobic oxidative CH functionalization of glycine derivatives with olefins and organoboranes has been established. The mild reaction has an excellent functional group tolerance, and exhibits a broad scope with respect to both glycine derivatives and the two types of nucleophilic components, allowing for the facile synthesis of diverse substituted quinolines and glycine derivatives bearing various patterns of functionalities in the α‐position. Abstract :