Director orientations in lyotropic liquid crystals: diffusion MRI mapping of the Saupe order tensor. Issue 12 (7th March 2016)

• Record Type: Journal Article
• Authors: Topgaard, Daniel
• Is Part Of: Physical chemistry chemical physics. Volume 18:Issue 12(2016)
• Page Start: 8545
• Page End: 8553
• Publication Date: 2016-03-07
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c5cp07251d
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : MRI with axisymmetric diffusion encoding enables spatially resolved quantification of domain orientations in surfactant-water liquid crystals with and without macroscopic orientational order. Abstract : The macroscopic physical properties of a liquid crystalline material depend on both the properties of the individual crystallites and the details of their spatial arrangement. We propose a diffusion MRI method to estimate the director orientations of a lyotropic liquid crystal as a spatially resolved field of Saupe order tensors. The method relies on varying the shape of the diffusion-encoding tensor to disentangle the effects of voxel-scale director orientational order and the local diffusion anisotropy of the solvent. Proof-of-concept experiments are performed on water in lamellar and reverse hexagonal liquid crystalline systems with intricate patterns of director orientations.