Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle. Issue 26 (14th March 2016)
- Record Type:
- Journal Article
- Title:
- Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle. Issue 26 (14th March 2016)
- Main Title:
- Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle
- Authors:
- Bergemann, N.
Pistidda, C.
Milanese, C.
Emmler, T.
Karimi, F.
Chaudhary, A.-L.
Chierotti, M. R.
Klassen, T.
Dornheim, M. - Abstract:
- Abstract : The hydride composite Ca(BH4 )2 –Mg2 NiH4 transfers all boron to MgNi2.5 B2 upon dehydrogenation, avoiding boron sinks. The rehydrogenation to Ca(BH4 )2 was confirmed. Abstract : The Ca(BH4 )2 –Mg2 NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4 )2 -based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5 B2 is formed upon dehydrogenation and the formation of Ca(BH4 )2 upon rehydrogenation is confirmed.
- Is Part Of:
- Chemical communications. Volume 52:Issue 26(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 26(2016)
- Issue Display:
- Volume 52, Issue 26 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 26
- Issue Sort Value:
- 2016-0052-0026-0000
- Page Start:
- 4836
- Page End:
- 4839
- Publication Date:
- 2016-03-14
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc09991a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2205.xml