Tuning the Mn valence state in new Ca0.66Mn2−xAlxO4 (x ≤ 0.4) oxides: impact on magnetic and redox properties. Issue 11 (9th February 2016)

• Record Type: Journal Article
• Authors: Lesturgez, Stéphanie; Goglio, Graziella; Weill, François; N'Guyen, Olivier; Toulemonde, Olivier; Durand, Etienne; Hernandez, Julien; Demourgues, Alain
• Is Part Of: Dalton transactions. Volume 45:Issue 11(2016)
• Page Start: 4647
• Page End: 4658
• Publication Date: 2016-02-09
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt02761f
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Al 3+ substitution for Mn 4+ /Mn 3+ into the Ca0.66 Mn2 O4 1D tunnel network leads to the stabilization of an orthorhombic unit cell (SG: Pnma ) with two different Mn sites attributed mainly to Mn 4+ and Mn 3+ respectively. Abstract : New Ca0.66 Mn2− x Al x O4 ( x ≤ 0.4) solid solutions crystallizing with the CaFe2 O4 -type structure (SG: Pnma ) were synthesized for the first time by the glycine-nitrate process. The structures were determined on the basis of XRD Rietveld analysis and electron diffraction investigation. While the CaMn3 O6 ('Ca0.66 Mn2 O4 ') oxide adopts a monoclinic unit cell, the Al substitution for Mn ( x = 0.2, 0.4) leads to an orthorhombic cell with only two Mn atomic positions, with different valence states, and 33% of Ca sites empty. The Ca molar concentration decreases down to 0.6 in order to increase the Mn valence leading to a phase mixture, whereas a slight Ca content increase up to 0.7 leads to a decrease of Mn valence in the pure phase. The Al 3+ ions are located at a specific Mn site because their ionic radii are close to that of Mn 4+ and a more isotropic environment. The unit cell parameters and volume strongly decrease for a low Al content and tend to an asymptotic value of x = 0.33–0.4, around the limit of solubility. As the Al content increases, the Mn valence state in the same slightly distorted octahedral site increases up to 4+ whereas the other octahedral site is highly elongated and corresponds mainly to Jahn–Teller Mn 3+ . At x = 0.33, these two Mn sites correspond to Mn 4+ and Mn 3+ respectively. Moreover, the aluminium content increase induces a weakening of the global antiferromagnetic long range interactions between the ferromagnetic chains. The Al substitution leads to the change of the Mn valence distribution as well as the unit cell symmetry of the CaMn3 O6 phase. These 1D tunnel networks stabilizing the Mn 3+ /Mn 4+ valence states can be reduced under Ar/5%H2 between T = 300 °C and T = 600 °C (heating rate = 2 °C min −1 ) into pure Mn 2+ rocksalt solid solution despite the large difference in ionic radii. The re-oxidation leads to the same CaFe2 O4 -type structure and several redox cycles can be operated. The relationship between the two double chains of the edge-sharing octahedral sites and the rocksalt-type framework is clear and should appear as the driving force for the structural transformation during the reduction/oxidation processes. Finally, Al substitution allows an increasing of the Mn–O bond covalence and consequently the reduction in temperature.