Two-step C–H, C–P bond activation at an α-diimine iron dinitrogen complex. Issue 24 (4th March 2016)
- Record Type:
- Journal Article
- Title:
- Two-step C–H, C–P bond activation at an α-diimine iron dinitrogen complex. Issue 24 (4th March 2016)
- Main Title:
- Two-step C–H, C–P bond activation at an α-diimine iron dinitrogen complex
- Authors:
- Ghosh, Chandrani
Groy, Thomas L.
Bowman, Amanda C.
Trovitch, Ryan J. - Abstract:
- Abstract : Thermolysis of newly prepared( Ph2PPr DI)Fe(N2 ) results in chelate C–H and C–P bond activation to yield phosphide-bridged dimers. Abstract : Reduction of 6-coordinate( Ph2PPr DI)FeBr2 under N2 results in formation of the terminal dinitrogen complex, ( Ph2PPr DI)FeN2 . Heating this product to 75 °C allows for C–H and C–P activation of the chelate to generate the cisoid and transoid isomers of [(μ-PrPPh-κ 5 -P, N, N, Cγ, P- Ph2PPr DI PrPPh )Fe]2 . Mechanistic possibilities for this transformation are discussed.
- Is Part Of:
- Chemical communications. Volume 52:Issue 24(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 24(2016)
- Issue Display:
- Volume 52, Issue 24 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 24
- Issue Sort Value:
- 2016-0052-0024-0000
- Page Start:
- 4553
- Page End:
- 4556
- Publication Date:
- 2016-03-04
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc09167e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 579.xml