Rigid Conjugated Twisted Truxene Dimers and Trimers as Electron Acceptors. (18th February 2016)

• Record Type: Journal Article
• Authors: Zhang, Gang; Lami, Vincent; Rominger, Frank; Vaynzof, Yana; Mastalerz, Michael
• Is Part Of: Angewandte Chemie. Volume 128:Number 12(2016)
• Page Start: 4045
• Page End: 4049
• Publication Date: 2016-02-18
• Subjects: Dimerisierung -- Elektronenakzeptoren -- Helizität -- Konjugation -- Truxene; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201511532
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: A new class of rigid twisted truxenone oligomers with an enlarged π backbone has been established by oxidative dimerization reactions. The resulting extended conjugated systems have large extinction coefficients and low‐lying LUMO levels and show good solubility in common organic solvents, thus making them attractive compounds as new electron acceptors in organic electronics. Their suitability as electron acceptors has been demonstrated in bulk‐heterojunction organic solar cells with poly({4, 8‐bis[(2‐ethylhexyl)oxy]benzo[1, 2‐b:4, 5‐b′]dithiophene‐2, 6‐diyl}{3‐fluoro‐2‐[(2‐ethylhexyl)carbonyl]thieno[3, 4‐b]thiophenediyl}) (PTB7) as the donor material.