Amino‐Functionalized Conjugated Polymer as an Efficient Electron Transport Layer for High‐Performance Planar‐Heterojunction Perovskite Solar Cells. Issue 5 (8th December 2015)

• Record Type: Journal Article
• Authors: Sun, Chen; Wu, Zhihong; Yip, Hin‐Lap; Zhang, Hua; Jiang, Xiao‐Fang; Xue, Qifan; Hu, Zhicheng; Hu, Zhanhao; Shen, Yan; Wang, Mingkui; Huang, Fei; Cao, Yong
• Is Part Of: Advanced energy materials. Volume 6:Issue 5(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2015-12-08
• Subjects: perovskite solar cells -- organic conjugated polymers -- electron transport layers -- planar‐heterojunction -- fullerenes replacement; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201501534
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : An amino‐functionalized copolymer with a conjugated backbone composed of fluorene, naphthalene diimide, and thiophene spacers (PFN‐2TNDI) is introduced as an alternative electron transport layer (ETL) to replace the commonly used [6, 6]‐Phenyl‐C61‐butyric acid methyl ester (PCBM) in the p–i–n planar‐heterojunction organometal trihalide perovskite solar cells. A combination of characterizations including photoluminescence (PL), time‐resolved PL decay, Kelvin probe measurement, and impedance spectroscopy is used to study the interfacial effects induced by the new ETL. It is found that the amines on the polymer side chains not only can passivate the surface traps of perovskite to improve the electron extraction properties, they also can reduce the work function of the metal cathode by forming desired interfacial dipoles. With these dual functionalities, the resulted solar cells outperform those based on PCBM with power conversion efficiency (PCE) increased from 12.9% to 16.7% based on PFN‐2TNDI. In addition to the performance enhancement, it is also found that a wide range of thicknesses of the new ETL can be applied to produce high PCE devices owing to the good electron transport property of the polymer, which offers a better processing window for potential fabrication of perovskite solar cells using large‐area coating method. Abstract : The fullerene electron transport layer is replaced by a thickness‐insensitive ­conjugated polymer in p–i–n planar hetero­junction perovskite solar cells. The amines of polymer side chains can both passivate the surface traps of perovskite and reduce the work function of the metal cathode. With these dual functionalities, the resulting solar cells show 16.7% power conversion efficiency (PCE), which outperforms those based on fullerene interlayers.