Use of crown ethers to isolate intermediates in ammonia-borane dehydrocoupling reactions. Issue 18 (8th February 2016)
- Record Type:
- Journal Article
- Title:
- Use of crown ethers to isolate intermediates in ammonia-borane dehydrocoupling reactions. Issue 18 (8th February 2016)
- Main Title:
- Use of crown ethers to isolate intermediates in ammonia-borane dehydrocoupling reactions
- Authors:
- Less, Robert J.
García-Rodríguez, Raúl
Simmonds, Hayley R.
Allen, Lucy K.
Bond, Andrew D.
Wright, Dominic S. - Abstract:
- Abstract : The presence of 18-crown-6 in the Lewis acid-promoted dehydrocoupling reaction of ammonia borane permits isolation of [(THF)BH2 NH3 ] + cation. Abstract : The presence of 18-crown-6 in the Lewis acid-promoted dehydrocoupling reaction of ammonia borane permits isolation of [(THF)BH2 NH3 ] + and [BH2 (NH3 )2 ] + cations. [(THF)BH2 NH3 ] + reacts with Lewis bases to give either boron adducts or by deprotonation at nitrogen to give borazine and ammonia-borane.
- Is Part Of:
- Chemical communications. Volume 52:Issue 18(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 18(2016)
- Issue Display:
- Volume 52, Issue 18 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 18
- Issue Sort Value:
- 2016-0052-0018-0000
- Page Start:
- 3650
- Page End:
- 3652
- Publication Date:
- 2016-02-08
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc00088f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2166.xml