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Asymmetric sequential Au(i)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles. Issue 20 (15th February 2016)
Record Type:
Journal Article
Title:
Asymmetric sequential Au(i)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles. Issue 20 (15th February 2016)
Main Title:
Asymmetric sequential Au(i)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles
Abstract : A gold-catalyzed enone-formation and asymmetric cyanosilylation sequence is developed, providing enantioenriched 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN). Abstract : An unprecedented sequential gold-catalyzed enone-formation and bifunctional tertiary amine mediated asymmetric cyanosilylation reaction is developed, allowing the highly enantioselective synthesis of 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).