Hybridization of graphene nanosheets and carbon-coated hollow Fe3O4 nanoparticles as a high-performance anode material for lithium-ion batteries. Issue 7 (29th January 2016)

• Record Type: Journal Article
• Authors: Zuo, Yongtao; Wang, Gang; Peng, Jun; Li, Gang; Ma, Yanqing; Yu, Feng; Dai, Bin; Guo, Xuhong; Wong, Ching-Ping
• Is Part Of: Journal of materials chemistry. Volume 4:Issue 7(2016)
• Page Start: 2453
• Page End: 2460
• Publication Date: 2016-01-29
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5ta09742h
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A novel 2D H-Fe3 O4 @C/GNS electrode exhibits excellent cycling stability and super high rate performance. Abstract : Fe3 O4 has long been regarded as a promising anode material for lithium ion batteries due to its high theoretical capacity, earth abundance, low cost, and nontoxic properties. At present, no effective method has been realized to overcome the bottleneck of poor cyclability and low rate capability because of its huge volume change and low electrical conductivity. In this article, a facile synthesis strategy is developed to fabricate two-dimensional (2D) carbon encapsulated hollow Fe3 O4 nanoparticles (H-Fe3 O4 NPs) homogeneously anchored on graphene nanosheets (designated as H-Fe3 O4 @C/GNSs) as a durable high-rate lithium ion battery anode material. In the constructed architecture, the thin carbon shells can avoid the direct exposure of encapsulated H-Fe3 O4 NPs to the electrolyte and preserve the structural and interfacial stabilization of H-Fe3 O4 NPs. Meanwhile, the flexible and conductive GNSs and carbon shells can accommodate the mechanical stress induced by the volume change of H-Fe3 O4 NPs as well as inhibit the aggregation of Fe3 O4 NPs and thus maintain the structural and electrical integrity of the H-Fe3 O4 @C/GNSs electrode during the lithiation/delithiation processes. As a result, the H-Fe3 O4 @C/GNSs electrode exhibits outstanding reversible capacity (870.4 mA h g −1 at a rate of 0.1C (1C = 1 A g −1 ) after 100 cycles) and excellent rate performance (745, 445, and 285 mA h g −1 at 1, 5, and 10C, respectively) for lithium storage. More importantly, the H-Fe3 O4 @C/GNSs electrode demonstrates prolonged cycling stability even at high charge/discharge rates (only 6.8% capacity loss after 200 cycles at a high rate of 10C). Our results show that the 2D H-Fe3 O4 @C/GNSs are promising anode materials for next generation LIBs with high energy and power density.