Hydride Reduction by a Sodium Hydride–Iodide Composite. (17th February 2016)
- Record Type:
- Journal Article
- Title:
- Hydride Reduction by a Sodium Hydride–Iodide Composite. (17th February 2016)
- Main Title:
- Hydride Reduction by a Sodium Hydride–Iodide Composite
- Authors:
- Too, Pei Chui
Chan, Guo Hao
Tnay, Ya Lin
Hirao, Hajime
Chiba, Shunsuke - Abstract:
- Abstract: Sodium hydride (NaH) is widely used as a Brønsted base in chemical synthesis and reacts with various Brønsted acids, whereas it rarely behaves as a reducing reagent through delivery of the hydride to polar π electrophiles. This study presents a series of reduction reactions of nitriles, amides, and imines as enabled by NaH in the presence of LiI or NaI. This remarkably simple protocol endows NaH with unprecedented and unique hydride‐donor chemical reactivity.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 11(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 11(2016)
- Issue Display:
- Volume 128, Issue 11 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 11
- Issue Sort Value:
- 2016-0128-0011-0000
- Page Start:
- 3783
- Page End:
- 3787
- Publication Date:
- 2016-02-17
- Subjects:
- Amide -- Decyanierung -- Dichtefunktionalrechnungen -- Natriumhydrid -- Reduktionen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201600305 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 673.xml