A functional mesoporous ionic crystal based on polyoxometalate. Issue 7 (25th January 2016)

• Record Type: Journal Article
• Authors: Kawahara, Ryosuke; Niinomi, Kazuma; Kondo, Junko N.; Hibino, Mitsuhiro; Mizuno, Noritaka; Uchida, Sayaka
• Is Part Of: Dalton transactions. Volume 45:Issue 7(2016)
• Page Start: 2805
• Page End: 2809
• Publication Date: 2016-01-25
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt04556h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A mesoporous ionic crystal is synthesized with a polyoxometalate and a macrocation with polar cyano groups. The compound possesses one-dimensional mesopores and shows high proton conductivity and catalytic activity, which are due to the water molecules in the mesopores. Abstract : A mesoporous ionic crystal is synthesized with a polyoxometalate and a macrocation with polar cyano groups. The compound possesses one-dimensional mesopores with an opening of 3.0 × 2.0 nm. The compound shows high proton conductivity and catalytic activity, which are due to the water molecules in the mesopores.