3D Bi2S3 salix leaf-like nanosheet/TiO2 nanorod branched heterostructure arrays for improving photoelectrochemical properties. Issue 9 (8th February 2016)

• Record Type: Journal Article
• Authors: Wan, Yanling; Han, Minmin; Yu, Limin; Yi, Gewen; Jia, Junhong
• Is Part Of: CrystEngComm. Volume 18:Issue 9(2016)
• Page Start: 1577
• Page End: 1584
• Publication Date: 2016-02-08
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c5ce02252e
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : We fabricate a peculiar 3D structure of Bi2 S3 salix leaf-like nanosheet/TiO2 nanorod branched heterostructure arrays by a convenient hydrothermal method and discussed their mechanism of improving photoelectrochemical cell (PEC) properties. Abstract : We firstly fabricated a peculiar 3D structure of Bi2 S3 salix leaf-like nanosheet/TiO2 nanorod branched heterostructure arrays by a convenient hydrothermal method and discussed their mechanism of improving photoelectrochemical cell (PEC) properties. The salix leaf-like Bi2 S3 nanosheets (NSs) were grown on TiO2 nanorod arrays through controlling the molar ratio of EDTA-Na2 /Bi 3+ and the reaction time. The morphology, crystal structure, microstructure and optical performance of the 3D Bi2 S3 NS/TiO2 NRs at different reaction times were investigated. The results show that the branched heterostructure of 3D Bi2 S3 NS/TiO2 NR arrays exhibits enhanced photocurrent density and optical absorption, which were attributed to the larger Bi2 S3 surface area, as well as a direct electron path within the salix leaf-like Bi2 S3 NS and TiO2 NR heterojunctions, resulting from more excitation sites of incident light. The photocurrent density of the 3D Bi2 S3 NS/TiO2 NR arrays was almost 9 times greater than that of pristine TiO2 without a branching structure. The results of the present work demonstrate that fabrication of the branched Bi2 S3 NS/TiO2 NR heterogeneous structure is a significant fabrication technology with great promise in PECs.