On the nature of the stabilisation of the E⋯π pnicogen bond in the SbCl3⋯toluene complex. Issue 17 (3rd February 2016)
- Record Type:
- Journal Article
- Title:
- On the nature of the stabilisation of the E⋯π pnicogen bond in the SbCl3⋯toluene complex. Issue 17 (3rd February 2016)
- Main Title:
- On the nature of the stabilisation of the E⋯π pnicogen bond in the SbCl3⋯toluene complex
- Authors:
- Lo, Rabindranath
Švec, Petr
Růžičková, Zdeňka
Růžička, Aleš
Hobza, Pavel - Abstract:
- Abstract : The characteristic features of pnicogen bonding are due to the concert action of attractive dispersion and electrostatic interactions. Abstract : The off-symmetrical structure of the toluene⋯SbCl3 complex is a consequence of the off-centre location of σ-holes at the Sb atom. DFT-SAPT calculations have been used to determine the total interaction energies and their components. The characteristic features of the pnicogen bonding are due to the concert action of electrostatic and dispersion interactions.
- Is Part Of:
- Chemical communications. Volume 52:Issue 17(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 17(2016)
- Issue Display:
- Volume 52, Issue 17 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 17
- Issue Sort Value:
- 2016-0052-0017-0000
- Page Start:
- 3500
- Page End:
- 3503
- Publication Date:
- 2016-02-03
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc10363k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 805.xml