Addition of silylated nucleophiles to α-oxoketenes. Issue 14 (19th January 2016)
- Record Type:
- Journal Article
- Title:
- Addition of silylated nucleophiles to α-oxoketenes. Issue 14 (19th January 2016)
- Main Title:
- Addition of silylated nucleophiles to α-oxoketenes
- Authors:
- Dudognon, Yohan
Presset, Marc
Rodriguez, Jean
Coquerel, Yoann
Bugaut, Xavier
Constantieux, Thierry - Abstract:
- Abstract : A general evaluation of silylated nucleophiles to intercept transient α-oxoketenes generated by microwave-assisted Wolff rearrangement of 2-diazo-1, 3-dicarbonyl compounds is presented. Abstract : A general evaluation of silylated nucleophiles to intercept transient α-oxoketenes generated by microwave-assisted Wolff rearrangement of 2-diazo-1, 3-dicarbonyl compounds is presented. Original scaffolds and synthetic intermediates are accessed in a rapid, efficient and easy-to-handle way. Mechanistic studies by DFT calculations and some post-functionalizations are discussed.
- Is Part Of:
- Chemical communications. Volume 52:Issue 14(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 14(2016)
- Issue Display:
- Volume 52, Issue 14 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 14
- Issue Sort Value:
- 2016-0052-0014-0000
- Page Start:
- 3010
- Page End:
- 3013
- Publication Date:
- 2016-01-19
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc10217k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1065.xml