Cobalt PNCNHC 'pincers': ligand dearomatisation, formation of dinuclear and N2 complexes and promotion of C–H activation. Issue 13 (13th January 2016)
- Record Type:
- Journal Article
- Title:
- Cobalt PNCNHC 'pincers': ligand dearomatisation, formation of dinuclear and N2 complexes and promotion of C–H activation. Issue 13 (13th January 2016)
- Main Title:
- Cobalt PNCNHC 'pincers': ligand dearomatisation, formation of dinuclear and N2 complexes and promotion of C–H activation
- Authors:
- Simler, Thomas
Braunstein, Pierre
Danopoulos, Andreas A. - Abstract:
- Abstract : Ligand dearomatisation in Co II phosphino-picoline NHC-type pincers and dicobalt complexes result from side-arm metalation or C–H activation at the NHC backbone; in the latter case, an 'anionic dicarbene' originates from a dearomatised Co I –N2 complex. Abstract : Studies of ligand dearomatisation in cobalt phosphino-picoline N-heterocyclic carbene (PNC NHC )-type pincers have revealed the formation of dinuclear cobalt complexes by either side-arm metalation or C–H activation at the NHC backbone; in the latter case, the product complex, featuring an 'anionic dicarbene', originated from a dearomatised Co I –N2 complex.
- Is Part Of:
- Chemical communications. Volume 52:Issue 13(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 13(2016)
- Issue Display:
- Volume 52, Issue 13 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 13
- Issue Sort Value:
- 2016-0052-0013-0000
- Page Start:
- 2717
- Page End:
- 2720
- Publication Date:
- 2016-01-13
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc10121b ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 491.xml