Highly diastereoselective approach to methylenecyclopropanes via boron-homologation/allylboration sequences. Issue 12 (7th January 2016)
- Record Type:
- Journal Article
- Title:
- Highly diastereoselective approach to methylenecyclopropanes via boron-homologation/allylboration sequences. Issue 12 (7th January 2016)
- Main Title:
- Highly diastereoselective approach to methylenecyclopropanes via boron-homologation/allylboration sequences
- Authors:
- Baumann, A. N.
Music, A.
Karaghiosoff, K.
Didier, D. - Abstract:
- Abstract : Unprecedented one-pot highly diastereoselective synthesis of methylenecyclopropanes via boron-homologation/boron-allylation sequences possessing a quaternary stereocenter. Abstract : A simple and efficient diastereoselective synthesis of methylenecyclopropanes is described, in which boron-homologation and allylboration are merged into a one-pot process, starting from in situ generated cyclopropenyllithium species. This unprecedented methodology opens a new route to strained alkylidenecycloalkanes containing a quaternary stereocenter, in high yields and excellent diastereomeric ratios.
- Is Part Of:
- Chemical communications. Volume 52:Issue 12(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 12(2016)
- Issue Display:
- Volume 52, Issue 12 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 12
- Issue Sort Value:
- 2016-0052-0012-0000
- Page Start:
- 2529
- Page End:
- 2532
- Publication Date:
- 2016-01-07
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc09904h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1952.xml