ChemInform Abstract: Regio‐, Diastereo‐, and Enantioselective Nitroso‐Diels—Alder Reaction of 1, 3‐Diene‐1‐carbamates Catalyzed by Chiral Phosphoric Acids. Issue 10 (February 2016)

• Record Type: Journal Article
• Authors: Pous, Jonathan; Courant, Thibaut; Bernadat, Guillaume; Iorga, Bogdan I.; Blanchard, Florent; Masson, Geraldine
• Is Part Of: ChemInform. Volume 47:Issue 10(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-02
• Subjects: oxazine derivatives -- cycloaddition reactions -- regioselective reactions -- diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) -- organocatalysis; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201610195
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: A series of cis‐3, 6‐disubstituted dihydro‐1, 2‐oxazines (III) is readily prepared by enantioselective nitroso‐Diels—Alder reaction of carbamate‐dienes (I) with nitrosoarenes (II) in the presence of chiral phosphoric acid BTIPA as a catalyst.