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ChemInform Abstract: Efficient Organocatalytic Construction of C4‐Alkyl Substituted Piperidines and Their Application to the Synthesis of (+)‐α‐Skytanthine. Issue 10 (February 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Efficient Organocatalytic Construction of C4‐Alkyl Substituted Piperidines and Their Application to the Synthesis of (+)‐α‐Skytanthine. Issue 10 (February 2016)
Main Title:
ChemInform Abstract: Efficient Organocatalytic Construction of C4‐Alkyl Substituted Piperidines and Their Application to the Synthesis of (+)‐α‐Skytanthine.
Abstract: The scalable three‐step reaction sequence of thiomalonamates and functionalized α, β‐unsaturated aldehydes in the presence of a chiral prolinol‐derived catalyst delivers the title products in high yields and with very high enantiomeric excesses.