Double-side responsive polymer near-infrared photodetectors with transfer-printed electrode. Issue 7 (26th January 2016)

• Record Type: Journal Article
• Authors: Xiong, Sixing; Tong, Jinhui; Mao, Lin; Li, Zaifang; Qin, Fei; Jiang, Fangyuan; Meng, Wei; Liu, Tiefeng; Li, Weiwei; Zhou, Yinhua
• Is Part Of: Journal of materials chemistry. Volume 4:Issue 7(2016)
• Page Start: 1414
• Page End: 1419
• Publication Date: 2016-01-26
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5tc04111b
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Transfer-printed conducting polymer (tp-CP) is employed as the top electrode for near-infrared organic photodetectors. The double-side responsive photodetector exhibits a detectivity of 10 13 Jones. Abstract : Low dark current is critical to realize high-performance near-infrared organic photodetectors (NIR-OPDs). In general, organic photodetectors (OPDs) are with vacuum-deposited metals as the top electrode. The deposition of such metal would inevitably form doping to the organic active layer and thus yield high dark current. Herein, we employ transfer-printed conducting polymer (tp-CP) as the top electrode instead of the vacuum-deposited metal electrode. The photodetector with tp-CP electrode exhibits over two orders of magnitude lower dark current density than the device with the vacuum-deposited metal electrode. The photodetector with tp-CP electrode displays a responsivity of 0.37 A W −1 at 850 nm and a low dark current density of 3.0 nA cm −2 at −0.2 V based on a near-infrared (NIR) active layer of PMDPP3T:PC61 BM that absorbs photons up to 1000 nm. The detectivity of the NIR photodetector reaches as high as over 10 13 Jones. Furthermore, the NIR photodetector is double-side responsive to incident light, either from the bottom or the top electrode, because the top tp-CP electrode shows similar transparency as the bottom indium-tin oxide electrode.