Mesoporous Pt nanospheres with designed pore surface as highly active electrocatalyst. Issue 2 (8th December 2015)

• Record Type: Journal Article
• Authors: Jiang, Bo; Li, Cuiling; Malgras, Victor; Imura, Masataka; Tominaka, Satoshi; Yamauchi, Yusuke
• Is Part Of: Chemical science. Volume 7:Issue 2(2016:Feb.)
• Page Start: 1575
• Page End: 1581
• Publication Date: 2015-12-08
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5sc03779d
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : A novel strategy for large-scale synthesis of shape- and size-controlled mesoporous Pt nanospheres (MPNs) through a slow reduction reaction in the presence of surfactant is reported here for the first time. Abstract : A novel strategy for large-scale synthesis of shape- and size-controlled mesoporous Pt nanospheres (MPNs) through a slow reduction reaction in the presence of surfactant is reported here for the first time. The slow reduction reaction exclusively results in well-defined mesoporous architectures distinctly different from the dendritic constructions reported previously. More importantly, abundant catalytically active sites are created on the highly accessible mesoporous surfaces by the selective adsorption of bromide ions. The MPNs prepared by using the new synthetic route not only show superior electrochemical performance toward methanol oxidation reaction and oxygen reduction reaction, but also exhibit extremely high structural thermostability, which makes them promising catalysts for industrial applications.