Novel indenyl ligands bearing electron-withdrawing functional groups. (3rd November 2015)

• Record Type: Journal Article
• Authors: Honzíčková, Iva; Vinklárek, Jaromír; Romão, Carlos C.; Růžičková, Zdeňka; Honzíček, Jan
• Is Part Of: New journal of chemistry. Volume 40:Number 1(2016:Jan.)
• Page Start: 245
• Page End: 256
• Publication Date: 2015-11-03
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c5nj02406d
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : A new family of molybdenum complexes with an unprecedented substitution pattern in the indenyl ligand is reported. Abstract : A series of molybdenum complexes bearing new ligands is reported. The study covers a series of molybdenum compounds with the η 5 -coordinated indenyl ligand substituted with acyl-, ester- and amide-functions. This portfolio was extended by adding one representative with a η 3 -coordinated ester-substituted indenyl ligand. The functionalized indenes, necessary for the assembly, were prepared by convenient routes starting from inexpensive and readily available materials, enabling their production on a multigram scale. All structural types presented in this experimental study were supported by X-ray crystallographic data.